Vieillissement des cellules à base de mélanges de colorant. [] A. Kay, M. Gratzel, Solar Energy Materials and Solar Cells 44 (). 11 oct. électrochimique en développant la première DSSC, une des cellules solaire troisième génération, formée d’un film de TiO2 (photo-. L’invention concerne une nouvelle cellule Graetzel (ou DSSC: une cellule solaire sensibilisée par un colorant) dotée d’un système de remplissage à la fois de.

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Such systems suffer noticeable decreases ee efficiency as the cells heat up internally. Another issue is that in order to have a reasonable chance of capturing a photon, the n-type layer has to be fairly thick. This is achieved through the use of nanotechnology and the conversion of the liquid electrolyte to a solid. The electrons flow toward the transparent electrode where they are collected for powering a load. Archived from the original on 28 September By country List of countries by photovoltaics production.

Growth of photovoltaics Timeline of solar cells.

A critical assessment of the learning curve”. In this case the liquid electrolyte is replaced by one of several solid hole conducting materials. The results are still promising since the tandem DSC was in itself rudimentary. Archived from the original on Researchers have found that using dyes comprising a perylenemonoimide PMI as the acceptor and an oligothiophene coupled to triphenylamine as the donor greatly improve the performance of p-DSC by reducing charge recombination rate following dye-sensitized hole injection.


The DSSC has a number of attractive features; it is simple to make using conventional roll-printing techniques, is semi-flexible and semi-transparent which offers a variety of uses not applicable to glass-based systems, and most of the materials used are low-cost. Dyesol Director Gordon Thompson said, “The materials developed during this joint collaboration have the potential to significantly advance the commercialisation of DSC in a range of applications where performance and stability are essential requirements.

Cellule de Graetzel by Anthony Boitsios on Prezi

This creates a path to the immediate commercial utilisation of these new materials. Newer versions were quickly introduced circa that had much wider frequency response, notably “triscarboxy-ruthenium terpyridine” [Ru 4,4′,4″- COOH 3 -terpy NCS 3 ], which is efficient right into the low-frequency range of red and IR light.

The energy conversion efficiency of the device is 1. These include the use of quantum dots for conversion of higher-energy higher frequency light into multiple electrons, using solid-state electrolytes for better temperature response, and changing the doping of the TiO 2 to better match it with the electrolyte being used.

DSSCs degrade when exposed to ultraviolet radiation. An article published in Nature Materials demonstrated cell efficiencies of 8. Wayne Campbell at Massey UniversityNew Zealand, has experimented with a wide variety of organic dyes based on porphyrin.

The excited electrons are injected into the conduction band of the TiO 2 electrode. With an optimized concentration, they found that the overall power conversion efficiency improved from 5. The damage could be avoided cellu,e the addition of an appropriate barrier. Grid-connected photovoltaic power system List of photovoltaic power stations. The bond is either an ester, chelating, or bidentate bridging linkage.


Dye-sensitized solar cell

In silicon, sunlight can provide enough energy to push ed electron out of the lower-energy valence band into the higher-energy conduction band. The TiO 2 is chemically bound by a process called sintering. More importantly, the device was stable under thermal stress and soaking with light.

The first successful solid-hybrid dye-sensitized solar cells were reported.

The incident photon is absorbed by Ru complex photosensitizers adsorbed on the TiO 2 surface. On top is a transparent anode made of fluoride-doped tin dioxide SnO 2: The Journal of Physical Chemistry C.

Dye-sensitized solar cells separate the two functions provided by silicon in a traditional cell design. The efficiency of a DSSC depends on fraetzel energy levels of the component: Solar cells Nanocrystal graetzwl cell Organic solar cell Quantum dot solar cell Hybrid solar cell Plasmonic solar cell Carbon nanotubes in photovoltaics Dye-sensitized solar cell Cadmium telluride photovoltaics Copper indium gallium selenide solar cells Printed solar panel Perovskite solar cell.

Several important measures are used to characterize solar cells. These results are well within the limit for that of traditional inorganic silicon solar cells.